Scripted and directed by Kabir Sadanand, the ad is a sequel to the last edition of the Matrix Forex TV commercial.
Set in a courtroom, the ad shows Shahrukh Khan as a criminal and Juhi as a judge.
The duo were last seen together in 2008 film Bhootnath and this is said to be their first commercial together.
Both of them became business partners with Dreamz Unlimited before Shahrukh Khan took it over in 2004 and made it Red Chillies Entertainment. Now Shah Rukh, Juhi and her husband Jai Mehta are co-owners of Indian Premier League (IPL) franchise Kolkata Knight Riders.
Set to be aired soon, the advertisement also features cricketers Brett Lee, Yusuf Pathan and Brendon McCullum.